Methanol{2-methoxy-6-[(2-oxidopropyl)iminomethyl]phenolato}dioxidomolybdenum(VI)
نویسندگان
چکیده
In the structure of the title compound, [Mo(C(11)H(13)NO(3))O(2)(CH(3)OH)], the Mo(VI) ion is octahedrally coordinated by two oxide O atoms, the N atom and two deprotonated OH groups of the tridentate Schiff base ligand 2-meth-oxy-6-[(2-oxidoprop-yl)imino-meth-yl]phenolate and by a methanol O atom. In the crystal structure, two complexes are linked via O-H⋯O hydrogen bonds, yielding a centrosymmetric arrangement involving the methanol hydr-oxy group and one of the ligand O atoms coordinated to the Mo(VI) ion.
منابع مشابه
catena-Poly[[{2-methoxy-6-[(4-methylphenyl)iminomethyl]phenolato}cadmium(II)]-di-μ2-chlorido-[dimethanolcadmium(II)]-di-μ2-chlorido-[{2-methoxy-6-[(4-methylphenyl)iminomethyl]phenolato}cadmium(II)]-di-μ2-chlorido]
The structure of the title compound, [Cd(3)Cl(6)(C(15)H(15)NO(2))(2)(CH(4)O)(2)](n), is based on a layered zigzag polymeric chain along the c axis. The Cd(II) ions are linked by double chlorine bridges alternating between one CdCl(4)(CH(3)OH)(2) and two CdCl(4)(C(15)H(15)NO(2)) octa-hedral coordination units. Additional intrachain N-H⋯O and O-H⋯Cl hydrogen-bond interactions stabilize this arran...
متن کاملBis(μ-6-methoxy-2-{[(3-oxidopropyl)imino]methyl}phenolato)nickel(II) methanol monosolvate
The mol-ecular structure of the title complex, [Ni2(C11H13NO3)2]·CH3OH, contains two Ni(II) atoms and two doubly deprotonated 6-meth-oxy-2-{[(3-oxidoprop-yl)imino]-meth-yl}phenolate ligands. The Ni(II) atoms are each four-coordinated in a distorted square-planar geometry by three O atoms and one N atom derived from the phenolate ligands. The solvent mol-ecule is linked to the complex mol-ecule ...
متن کاملBis{(E)-2-methoxy-6-[(4-methylphenyl)iminomethyl]phenolato}zinc(II)
The title compound, [Zn(C(15)H(14)NO(2))(2)], contains a four-coordinate Zn atom located on a twofold rotation axis that exhibits a distorted tetra-hedral geometry by two phenolate O atoms and two azomethine N atoms of the Schiff base 2-methoxy-6-[(4-methyl-phen-yl)imino-meth-yl]phenolate ligands.
متن کامل[2-({Benzyl[2-(benzyl{5-methyl-2-oxido-3-[(pyridin-2-ylmethyl)iminomethyl]benzyl}amino)ethyl]azaniumyl}methyl)-4-methyl-6-[(pyridin-2-ylmethyl)iminomethyl]phenolato]nickel(II) perchlorate methanol disolvate
In the solvated title complex, [Ni(C(46)H(47)N(6)O(2))]ClO(4)·2CH(4)O, the coordination sphere around the Ni(II) ion can be described as distorted cis-NiO(2)N(4) octa-hedral defined by two phenolate O atoms and four N atoms from the hexa-dentate ligand. An intra-molecular bifurcated N-H⋯(N,O) hydrogen bond helps to establish the conformation of the complex mol-ecule. In the crystal, the compone...
متن کاملBis(2-methoxy-6-{[2-(methylammonio)ethyl]iminomethyl}phenolato)thiocyanatozinc(II) thiocyanate hemihydrate
The title mononuclear zinc(II) complex, [Zn(C(11)H(16)N(2)O(2))(2)(NCS)]NCS·0.5H(2)O, consists of a complex cation, a thio-cyanate anion, and half of a water mol-ecule. The Zn(II) atom in the cation is five-coordinated by two imine N and two phenolate O atoms from two bidentate Schiff base ligands, and by one N atom of a thio-cyanate ligand, forming a distorted trigonal-bipyramidal geometry. Th...
متن کامل